When
a flowline is shut down, very quickly liquid settles into ‘dips’
and gas rises to the ‘humps’ and then the system gradually
cools to the ambient temperature. As gas has a much lower
heat capacity than liquid, sections filled with gas cool much quicker
than those filled with liquid.
Cooldown can be a cause for concern in subsea and especially deepwater
developments due to the potential for hydrate formation. Hydrates
are crystalline compounds that form when water molecules encage
light hydrocarbons such as methane, ethane, or propane at high pressures
and low temperatures. Figure 1 is a plot of a typical hydrate
dissociation curve, to the left hand side of which hydrates may
exist, this is often referred to as the hydrate envelope.
Figure 1 Typical Hydrate Curve

In most deepwater oil developments, hydrates are avoided during normal
operation using insulation to maintain the fluid temperature above
the hydrate dissociation temperature at the operating pressure.
During a shutdown however, if the fluids are held at pressure they
may cool down into the hydrate envelope.
Cooldown
animation gif (826K)
This
animation shows the results from a simulation of a multiphase flowline
being shut in (at time zero) and allowed to cool to the ambient
temperature.
Very
soon after shut-in, the gas and liquid settle into peaks and troughs
in the flowline geometry, respectively. The geometry for this
system was a horizontal flowline to which was added a saw-tooth
undulation of 1m amplitude, 500m wavelength (i.e. distance between
peaks). Such an undulation is very gentle and may not be resolved
in topography data. However, even gentle undulations can influence
where the liquids and gas settle and hence the cooldown result.
The different cool down rates arising because
of the differing fluid heat capacities are seen as the animation
progresses; the temperature profile of the flowline mimics the hold-up
profile.
What
can also be seen in this animation is how the liquid levels in each
dip fluctuate and interact with each other. In effect, the
system is a series of manometers connected in series.
Consequently,
in order to calculate exactly which section cools first one must
predict exactly where the gas and liquid settle and how they move
after shut-in. To do this requires a detailed and accurate
topographical profile and a transient flowline simulator that can
accurately capture how these systems behave.
Unfortunately, accurate profiles of the pipeline in the as-built
condition are seldom available even if we believe the results of
the commercially available transient simulators!
Therefore, predicting the effect of gas-liquid distribution
on cooldown behaviour is usually meaningless.
What is required is a pragmatic approach to the problem. Such an approach has been developed by FEESA and is described in Life
of Field Cooldown in a Deepwater Development Case Study.