The
wax present in crude oils consists mainly of paraffin hydrocarbons
(C20 – C40) and naphtenic hydrocarbons (C30 – C60). Under certain conditions of temperature and pressure, these components
will come out of solution and form crystals of wax. In addition, waxy crudes also contain a
variety of other compounds, such as light and intermediate hydrocarbons
and heavy organics (resins, asphaltenes, diamondoids).
The
deposition of wax in pipelines can eventually lead to the pipeline
becoming blocked and unable to transport production fluids. It is usually the case that pipelines are
designed to operate at temperatures above the crude oil wax appearance
temperature (WAT). Fluid
temperatures are maintained by the application of insulation to
conserve heat. However on occasions, wax deposition is
prevented by the injection of special chemicals called ‘wax
inhibitors’ that help to maintain the wax components in
solution. In addition, many crudes contain only relatively
small concentrations of wax components such that protracted periods
of operation may elapse before the pipeline becomes blocked. Under these circumstances, the operator
may elect to allow the pipeline to build up wax, preferring to
periodically clean the pipeline in one way or another (usually
by pigging).
To
strengthen Maximus’ Flow Assurance capability, we have also
accessed MULTIFLASH’s wax formation methods. Hence, it is possible in Maximus to predict the boundaries
between regions where wax solid will and will not form. This allows designers and operators, to
define envelopes of safe operation that avoid problems associated
with wax. This feature
provides particular benefits in the design and operation of production
systems that gather together fluids with different waxing potential. If the separate wellstream fluids are adequately
characterised, then Maximus is able to predict whether wax will form in downstream pipelines
containing commingled fluids. This is a common scenario which is easy to assess with Maximus but which presents
difficulties for other commercially available software.
Below
is an example of a phase diagram generated using the MULTIFLASH methods integrated in Maximus. The diagram was generated using a live oil
composition and shows the wax formation curve crossing the bubblepoint
curve. Wax is predicted to form to the left of the boundary shown.
Example
Phase Diagram showing Wax Formation